Lewis Smith, Science Reporter
Grab an Italian masterpiece for less

The imagination is the only limit for a new material that can mend itself when ripped. In hospitals it could add durability to artificial bones and around the house it heralds the prospect of unbreakable glass and unchippable paint. But for half the population there is no disputing its most tantalising promise: the era of the self-repairing laddered stocking may be upon us.
Torn clothes, especially tights, which are all too often laddered when it is too late to change, can ruin an evening, but scientists have offered hope to those who fear being unable to look their best.
A research team has created an elastic substance that can mend itself as much as a week after being broken thanks to its arrangement of molecules. The torn ends are simply pushed together and allowed a little time to bond. After 15 minutes the join can be as good as new.
“I think it will have all sorts of uses,” said Professor Ludwik Leibler, one of the researchers behind the invention. “It’s just a matter of using your imagination. We have only just begun to think of what can be done with it.
“Stockings are a very good idea. It could be used in glass vases so they don’t break when your children knock them over - it could make the glass bouncy.”
Professor Leibler and his colleagues at the Industrial Physics and Chemistry Higher Educational Institution in Paris are convinced that it has potential for use in a wide range of applications. They are most hopeful of adapting the technology in medicine, where self-healing properties would be invaluable for artificial bone and cartilage.
The technology could also be applied to paint and other coatings, saving householders and car owners the expense of repairing chips and nicks. Its use in pipes would make plumbing repairs easier, perhaps sealing leaks before they became serious. The substance, which has taken five years to develop, is ready for commercial use, Professor Leibler says. This is expected to be in plastics.
The material mimics the elastic qualities of rubber but with the advantage of having “sticky ends” when a break occurs. The substance has small molecules arranged in a network that stretch but will return to its original shape. Once the broken ends are pushed together they start healing because the molecular make-up is such that the surfaces have lifelike attributes and seek to form bridges.
The research team reported their invention of the “supramolecular rubber” in the journal Nature. “These materials can be easily processed, reused and recycled. Their unique self-repairing properties, the simplicity of their synthesis, their availability from renewable resources and the low cost of raw ingredients bode well for future applications.”
They added that the material behaved like a rubber but “exhibits unique self-healing properties: when a sample is broken or cut into pieces and the pieces are brought into contact together for some time at room temperature (20C, 68F) they self-heal without the need to heat or press strongly. The process of breaking and healing can be repeated many times.”
The maximum time the ends can be left before it becomes impossible for them to repair themselves reduces as temperatures rise. At 23C they can be left for more than a week but at 40C the time falls to 48 hours. The longer the surfaces are left to fuse, the stronger the repair, but even after 15 minutes of bonding the material could still be stretched to three times its normal length before snapping.
Industry sectors news at a glance. Interactive heatmap, video and podcast
Everything the Business Traveller needs to know to make a better trip
Get ready for the winter sports season, with our resort guides and snow reports
We are backing British business, what is the confidence of the nation and what businesses are succeeding?
Growing demand for energy, oil that is harder to reach and the rise of carbon dioxide emissions. We examine the energy challenge
Enjoy further reading from Travel to Fashion, Business to Sport, discover more
Shortcuts to help you find sections and articles
1998
£47,955
12 months for the price of 11 and a 5% discount.
Offer ends 31/11/09
Check your free Experian credit report before applying
Car Insurance
to £60K + bonus (OTE £90k)
Lord Search & Selection
Location Flexible
If interested, call Oliver Luscombe on 0207 212 3065
PwC
£85k
CPA
Highly Competitve
Specsavers
Whiteley, near Southampton
Moments from Battersea Park.
For sale with Winkworth
Find out about shared ownership.
See your free Experian credit report beforehand
Book now & save over £100pp.
11 cool resorts, lowest prices... Early Booking offers 15 Nov.
20% off selected Azores holidays taken in October with Sunvil Discovery
Get covered on your travels with a superb range of policies at great prices. Visit InsureandGo.com
World Class Golf, Spa and preferential Beach Club. Private estate overlooking West Coast
Villas from £275 per night inclusive of Golf
Contact our advertising team for advertising and sponsorship in Times Online, The Times and The Sunday Times, or place your advertisement.
Times Online Services: Dating | Jobs | Property Search | Used Cars | Holidays | Births, Marriages, Deaths | Subscriptions | E-paper
News International associated websites: Globrix Property Search | Milkround
Copyright 2009 Times Newspapers Ltd.
This service is provided on Times Newspapers' standard Terms and Conditions. Please read our Privacy Policy.To inquire about a licence to reproduce material from Times Online, The Times or The Sunday Times, click here.This website is published by a member of the News International Group. News International Limited, 1 Virginia St, London E98 1XY, is the holding company for the News International group and is registered in England No 81701. VAT number GB 243 8054 69.