Lewis Smith, Science Reporter
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The imagination is the only limit for a new material that can mend itself when ripped. In hospitals it could add durability to artificial bones and around the house it heralds the prospect of unbreakable glass and unchippable paint. But for half the population there is no disputing its most tantalising promise: the era of the self-repairing laddered stocking may be upon us.
Torn clothes, especially tights, which are all too often laddered when it is too late to change, can ruin an evening, but scientists have offered hope to those who fear being unable to look their best.
A research team has created an elastic substance that can mend itself as much as a week after being broken thanks to its arrangement of molecules. The torn ends are simply pushed together and allowed a little time to bond. After 15 minutes the join can be as good as new.
“I think it will have all sorts of uses,” said Professor Ludwik Leibler, one of the researchers behind the invention. “It’s just a matter of using your imagination. We have only just begun to think of what can be done with it.
“Stockings are a very good idea. It could be used in glass vases so they don’t break when your children knock them over - it could make the glass bouncy.”
Professor Leibler and his colleagues at the Industrial Physics and Chemistry Higher Educational Institution in Paris are convinced that it has potential for use in a wide range of applications. They are most hopeful of adapting the technology in medicine, where self-healing properties would be invaluable for artificial bone and cartilage.
The technology could also be applied to paint and other coatings, saving householders and car owners the expense of repairing chips and nicks. Its use in pipes would make plumbing repairs easier, perhaps sealing leaks before they became serious. The substance, which has taken five years to develop, is ready for commercial use, Professor Leibler says. This is expected to be in plastics.
The material mimics the elastic qualities of rubber but with the advantage of having “sticky ends” when a break occurs. The substance has small molecules arranged in a network that stretch but will return to its original shape. Once the broken ends are pushed together they start healing because the molecular make-up is such that the surfaces have lifelike attributes and seek to form bridges.
The research team reported their invention of the “supramolecular rubber” in the journal Nature. “These materials can be easily processed, reused and recycled. Their unique self-repairing properties, the simplicity of their synthesis, their availability from renewable resources and the low cost of raw ingredients bode well for future applications.”
They added that the material behaved like a rubber but “exhibits unique self-healing properties: when a sample is broken or cut into pieces and the pieces are brought into contact together for some time at room temperature (20C, 68F) they self-heal without the need to heat or press strongly. The process of breaking and healing can be repeated many times.”
The maximum time the ends can be left before it becomes impossible for them to repair themselves reduces as temperatures rise. At 23C they can be left for more than a week but at 40C the time falls to 48 hours. The longer the surfaces are left to fuse, the stronger the repair, but even after 15 minutes of bonding the material could still be stretched to three times its normal length before snapping.
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Wow, I'm guessing very light reforming metal and zero point gravity will be next. I did not no France had "one" go down over there also. I hope "they" don't come down one day with a patent lawyer. YooouuuKnooowWhat I'm talking about. If you just came up with this wonderful invention by accident, that's one thing but if this took awhile like I think it would. Then why say "we have only just begun to think of what we can do with it" I would have been thinking of what to do with it the day I understood what I was creating. Unless you just did some sort of reverse engineering thingy? You know what I'm talking about. See ya on the dark side!
kevin, burke, virginia
Again, the French lead the way, this time through the imagination, skills, and persistence of Professor Ludwik Leibler, a physicist with an impressive list of well-earned prizes.
And who is a product of the Polish education system, if memory serves. But he was smart enough to see a better opportunity in France so I suppose that's a kind of French leadership.
And yes, I understand well that American universities and research organizations are staffed with large numbers of great scientists and engineers from all over the world.
Which is why I'm a bit hesitant to claim the Americans lead the way in any particular field.
GJL, Madison, USA
It just goes to show where our imagination can lead us when we are focused - what next?
I wonder how Prof Leibler's creative processes were kick-started on stockings.?
C Markus-Greene, Glasgow, Scotland
Wow, an amazing new item that might have a multitude of uses to benefit society, and all you can do is look out for tights that'll repair themselves.
David Leslie, Perth, Scotland
Perhaps one of the more mundane applications but one which none of us could live without might be shock absorbtion wherein this new rubber could repeatedly stretch and absorb mechanical energy in various axis and return to its original parameters over time.
What of its wear resistance for use in tyres?
Imagine it applied to automotive chassis, bumpers and body parts.
Incorporated into building materials it might repeatedly absorb the shock of earthquakes making load-bearing structures more flexible during the event yet returning them to their original state afterwards.
Again (like with the TGV) the French lead the way!
Larry, Middletown, USA/NY
I'm in my late 50's and I can remember my mum telling me as a child that stockings were made during the 1930-40's that didnt ladder but went into minute holes. My grandfather was a Hosiery dyers labourer he bought a pair of stockings home to prove the point to my nan, it later transpired that the hosiery manufacturer nearly went bankrupt because ladies were not replacing their stockings as often.. thanks to the new design of nylon thread and the weaving process. The Alec Guiness film (1951) "The Man in the White Suit" springs to mind a fabric that never wore out or became soiled etc.
Dawn Gregory, Hampshire, UK